If you can, you should always charge during off-peak hours to make it easier on the utility grid. Off-peak electricity is cheaper to procure wholesale during off-peak hours, and lower costs for your utility means lower rates for you in the long run. Also, off-peak generation tends to be more efficient and uses "cleaner" parts of the generation fleet as opposed to on-demand peak units. Basically, you're doing the environment a solid when you use electricity off-peak as much as possible.