In theory, yes, but Tesla won't do the install like that. They will argue (rightfully) that you could overtax the powerwall inadvertently and they still have to service it under warranty.
Makes sense. And I have no problem buying a second Powerwall. But, the California 2020 fire code that requires systems over 20 kW are 3 foot from any wall or each other. That is not going to be easy or maybe not feasible in our home.