Yes, it's quite possible that your 150 amp service is limiting the combined discharge rate of your Powerwall 3 units. Here's why:
A 150 amp service at 240 volts can theoretically provide a maximum power of 36 kW (150A × 240V = 36,000W or 36 kW). However, the National Electrical Code (NEC) requires that the total load on a service panel not exceed 80% of its rated capacity for continuous loads. This means that your 150 amp service can safely handle a continuous load of up to 28.8 kW (36 kW × 0.8 = 28.8 kW).
If each Powerwall 3 has a max discharge rate of 11.5 kW, then four units could potentially deliver a combined 46 kW (11.5 kW × 4 = 46 kW). This exceeds the safe continuous load capacity of your 150 amp service.
The 18 kW total discharge rate you're observing might be a result of the system limiting the output to prevent overloading your 150 amp service. Upgrading to a 200 amp service would provide a higher capacity:
200A × 240V = 48 kW
48 kW × 0.8 = 38.4 kW (safe continuous load for 200A service)
With a 200 amp service, your electrical system would be able to safely handle the combined maximum discharge rate of your four Powerwall 3 units (up to 46 kW), allowing you to take full advantage of their power output capabilities.