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I don't remember... it was probably some Derek Trucks Band or something like that... I can tell you the first song I played for my fiance when she got in the car though (I sing it to her a lot to make her laugh)
I remember this well as for me...I too planned it ahead of time. After my phone was linked up, it was queued up and ready. Drove away to Aerosmith Sweet Emotion on 11!!
Unfortunately the wife wasnt keen on the name "Little Suzi" for the car, so we settled on 'Voodoo" instead. But yeah, that didn't stop me from blasting this tune as we drove off for the first time.