At the moment, there isn't a VPP event showing in the app for today, but in the very likely event that one does happen than I am 95% yes.
I was questioning this yesterday when around 4:00pm outages hit nearby to me in Morgan Hill and San Martin that lasted about 6 hours from the Nextdoor posts for most, with a couple of small blocks with 3-10 homes on the outage map this morning.. The area that I am in was built up less than 20 years ago and is all underground, so I think the reliability should be good. Since my PTO in Oct 2020, the longest outage was only an hour.
If I am feeling nervous, I might move my reserve from 5% to 35% which which should keep everything but the A/C that isn't backup up anyway (LRA is too high) working until the sun comes back up in the morning.