OP, If I was planning your installation, I would have a dedicated trench for the rooftop PV and feed that from the GW2 in the house garage. With 330' of separation, the PV is the only thing that could be that far from the rest of the equipment.
I would put PW(s), GW2 in the house garage, or near wherever the feed is coming in from the 600A service to the house loads subpanel. Then run the long length from a dedicated 100A PV Generation subpanel from the shop to the main house and land in the GW2. With a 330' run you will need to upsize the PV subfeed to avoid voltage drop. This assumes you have the ability to install a new subfeed from home to the shop, which is probably a ton of work if you arent in the middle of your build, unless you have an open conduit you can use.
Tesla likes to make things simple and easy, but there is no reason the PW2 need to be near the service, though they can be.
We have a customer with 800A split phase service that we just expanded his first 6 Powerwall system which is 1100' away from his msp. We are planning another GW2 and another 6 Powerwalls. This new 6 PW system is attached to the service bunker and new 20 kW ground mount PV is about 80' from the service.
As far as the service topography with 240V 3 phase Delta, as long as the legs that you connect to show 120v to neutral, then you are on the correct 2 phases, assuming the service transformer is laid out like
@CrazyRabbit shows below. An installer would want to connect only to Phase A and Phase C. Phase B is 208V to neutral, hence the "High/Wild Leg"
When the 240V split phase power is derived from this, the 2 phases are 180 degrees apart as would be expected in a typical split-phase service.