If you're really paranoid about taking good care of the battery try this - charge it to 90% the night before you leave, then turn on "scheduled charging" and set it to like 5am or even 6am. Turn the charging limit up to 100%.
The car will top itself off early in te morning, up to 100%, and assuming you leave pretty quickly after that, you won't be leaving it at 100% charge very long, which is the main thing to avoid.
I personally would not charge it to 100% the night before, then leave it for 6-8hrs before driving it. In the first place, it's bad for the long-term battery life. Secondly, during those 6-8hrs while you're asleep, the car loses a few miles of charge! Better to charge it to 100% right before you drive it.